Match the essential plant macronutrient with its primary physiological role:
| List I (Nutrient) | List II (Primary Role) |
| P. Potassium | 1. Component of chlorophyll and ATP |
| Q. Magnesium | 2. Regulation of stomatal opening and water balance |
| R. Phosphorus | 3. Essential for cell wall structure |
| S. Calcium | 4. Energy transfer and root development |
Which of the following options correctly matches List I with List II?